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This research is targeted on defect-totally free kinking while in the germanium NW VLS progress, immediately after nucleation to your a Ge unmarried amazingly substrate, playing with Au-Ge catalyst liquid droplets from outlined proportions. Mathematical investigation of one’s fraction away from kinked NWs suggests the brand new dependence of kinking possibilities on the cable diameter and also the progress heat. The newest morphologies from kinked Ge NWs analyzed by electron microscopy reveal two line of, defect-free, kinking methods, whoever hidden mechanisms are said by using three-dimensional multiphase community simulations. Type I kinking, in which the gains axis changes away from vertical in order to ⟨۱۱۰⟩, is noticed in Ge NWs having an affordable diameter out of ∼۲۰ nm. It size coincides that have a significant diameter of which a natural change away from ⟨۱۱۱⟩ so you can ⟨۱۱۰⟩ progress occurs in the fresh phase profession simulations. Larger diameter NWs just display Type of II kinking, in which the gains axis alter from straight right to an more inclined ⟨۱۱۱⟩ axis inside 1st stages of cable growth.
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